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Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts
Shah, Mazloom; Guo, Qing-Xiang; Fu, Yao
2017
Source PublicationCATALYSIS COMMUNICATIONS
Volume89Issue:xPages:60-63
AbstractThe Pd, Ni, Ni-Sn, Cu and Ag@Pd nanocatalyst having different shape and size were used for direct dehydrogenation of cyclic ketones to the corresponding phenols in the presence of O-2 as the oxidant. Among all catalyst tested, metallic Pd-1 nanoparticles exhibited excellent catalytic performance both in presence and absence of p-toluenesulfonic acid. The dehydrogenation of cyclohexanone catalyzed by Pd-1 nanocatalyst led to a 93% yield of the desired cyclohexenone and phenol. X-ray diffraction (XRD) and transmission electron microscopy (TEM) confirmed that there was no change in morphology, crystal phases and particles size of Pd-1 nanocatalyst after the reaction.
KeywordPalladium Nanoparticles Heterogeneous Catalysts Dehydrogenation Cyclic Ketones Phenols
Language英语
Document Type期刊论文
Identifierhttp://ir.xtbg.org.cn/handle/353005/10309
Collection其他
Recommended Citation
GB/T 7714
Shah, Mazloom,Guo, Qing-Xiang,Fu, Yao. Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts[J]. CATALYSIS COMMUNICATIONS,2017,89(x):60-63.
APA Shah, Mazloom,Guo, Qing-Xiang,&Fu, Yao.(2017).Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts.CATALYSIS COMMUNICATIONS,89(x),60-63.
MLA Shah, Mazloom,et al."Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts".CATALYSIS COMMUNICATIONS 89.x(2017):60-63.
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