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title: Aerobic dehydrogenation of cyclic ketones into corresponding phenols catalyzed by heterogeneous Pd nanocatalysts
author: Shah, Mazloom;  Guo, Qing-Xiang;  Fu, Yao
Issued Date: 2017
Abstract: The Pd, Ni, Ni-Sn, Cu and Ag@Pd nanocatalyst having different shape and size were used for direct dehydrogenation of cyclic ketones to the corresponding phenols in the presence of O-2 as the oxidant. Among all catalyst tested, metallic Pd-1 nanoparticles exhibited excellent catalytic performance both in presence and absence of p-toluenesulfonic acid. The dehydrogenation of cyclohexanone catalyzed by Pd-1 nanocatalyst led to a 93% yield of the desired cyclohexenone and phenol. X-ray diffraction (XRD) and transmission electron microscopy (TEM) confirmed that there was no change in morphology, crystal phases and particles size of Pd-1 nanocatalyst after the reaction.
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Recommended Citation:
Shah, Mazloom,Guo, Qing-Xiang,Fu, Yao. Aerobic Dehydrogenation Of Cyclic Ketones Into Corresponding Phenols Catalyzed By Heterogeneous Pd Nanocatalysts[J]. Catalysis Communications,2017,89(X):60-63.

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