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title: Ionic liquid-coated enzyme for biocatalysis in organic solvent
author: Lee, JK;  Kim, MJ
Issued Date: 2002
Abstract: Ionic liquid-coated enzyme (ILCE) is described as a useful catalyst for biocatalysis in organic solvent. An ionic liquid, [PPMIM]-[PF6] (1, [PPMIM] = 1-(3'-phenylpropyl)-3-methylimidazolium), which is solid at room temperature and becomes liquid above 53 degreesC, was synthesized in two steps from N-methylimidazole. The coating of enzyme was done by simply mixing commercially available enzyme with 1 in the liquid phase above 53 degreesC and then allowing the mixture to cool. A representative ILCE, prepared with a lipase from Pseudomonas cepacia, showed markedly enhanced enantioselectivity without losing any significant activity.
Related URLs: 10.1021/jo026116q
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Recommended Citation:
Lee, JK,Kim, MJ. Ionic Liquid-coated Enzyme For Biocatalysis In Organic Solvent[J]. Journal Of Organic Chemistry,2002,67(19):6845-6847.

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