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Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis
Li, Yun-Wu; Ma, Hui-Yan; Wang, Su-Na; Xu, Jian; Li, Da-Cheng; Dou, Jian-Min; Bu, Xian-He
2015
Source PublicationRSC ADVANCES
ISSN2046-2069
Volume5Issue:108Pages:88809-88815
AbstractThree new Zn-II-ditetrazolate coordination polymers (CPs), namely [Zn(m-pdtz)(4,4'-bipy)(H2O)](n) (1), [Zn2Cl2(m-pdtz)(4,4'-bipy)](n) (2) and [Zn-2(OH)(2)(m-pdtz)](n) (3) (4,4'-bipy = 4,4'-bipyridine, m-H(2)pdtz = 5,5'-1,3-phenylene-ditetrazole), have been constructed by an in situ ditetrazolate-ligand synthesis system. The formation of m-pdtz(2-) ligand involves the Sharpless [2 3] cycloaddition reaction between isophthalonitrile (IPN) and NaN3 in the presence of Zn2 ions as Lewis-acid catalysts under hydro/solvothermal conditions. Single-crystal structural analyses reveal that compound 1 exhibits a new 6-connected 3D structural topology constructed from dimeric {Zn-2} clusters as secondary building units (SBUs), compound 2 represents a 2D sql structural feature built from rhombic tetrameric {Zn-4} rings as SBUs, while compound 3 displays a new (4,6)-connected 3D structural topology constructed from rod-shaped 1D Zn-chains as SBUs. Regarding these three CPs, we have performed a thorough investigation on their crystal structure, topology, and fluorescence property.
KeywordMetal-organic Frameworks Selective Gas-adsorption High Co2 Uptake Drug-delivery Hydrothermal Synthesis Hydrogen Storage Spin-crossover Pore-size Complexes Topology
Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.xtbg.org.cn/handle/353005/9813
Collection文献共享
Recommended Citation
GB/T 7714
Li, Yun-Wu,Ma, Hui-Yan,Wang, Su-Na,et al. Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis[J]. RSC ADVANCES,2015,5(108):88809-88815.
APA Li, Yun-Wu.,Ma, Hui-Yan.,Wang, Su-Na.,Xu, Jian.,Li, Da-Cheng.,...&Bu, Xian-He.(2015).Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis.RSC ADVANCES,5(108),88809-88815.
MLA Li, Yun-Wu,et al."Structure modulation in zinc-ditetrazolate coordination polymers by in situ ligand synthesis".RSC ADVANCES 5.108(2015):88809-88815.
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